Barley intended for the production of malt; therefore, the barley must be evaluated on the basis of its germinative capacity.
Under the influence of oxygen, which is liberated through the degradation of hydrogen peroxide, the barley kernels emerge from dormancy. In this way, germination can be induced at any given time.
Determination of hydrogen peroxide (H2O2) in disinfectants.
Suitable for all solutions that contain hydrogen peroxide (H2O2) but do not contain any other peroxides.
The quantitative determination is carried out in a sulphuric acid solution by titration with potassium permanganate:
5 H202 + 2 KMnO4 + 3 H2S04 → 2 MnSO4 + H2S04 + 8 H20 + 5 02
If the sample contains other peroxide-containing disinfectants in addition to hydrogen peroxide (H2O2), the method T-754-01-032 Peracetic-acid-based-disinfectants must be used.
Determination of hydrogen peroxide (H2O2) in disinfectants.
Suitable for all solutions that contain hydrogen peroxide (H2O2) but no other peroxides.
Hydrogen peroxide oxidizes iodide to iodine, which is reduced by sodium thiosulfate (Na2S2O3) and recalculated as hydrogen peroxide.
H2O2 + 2 NaI +H2SO4 |
→ |
I2 + Na2SO4 + 2 H2O |
I2 + Na2S2O3 |
→ |
2 NaI + Na2S2O3 |
If the sample contains other peroxide-containing disinfectants in addition to hydrogen peroxide (H2O2), the method T-757-01-032 Peracetic-acid-based-disinfectants must be used.
Determination of peracetic acid (C2H4O5) in disinfectants.
Suitable for all solutions containing peracetic acid (C2H4O5).
In addition to peracetic acid (C2H4O5), hydrogen peroxide (H2O2) is always present in disinfectants, so that both components must be determined together. The quantitative determination of hydrogen peroxide is carried out as described under T-753.01.032 Disinfectants-containing-hydrogen-peroxide-potassium-permanganate-method or T-753.02.032Disinfectants containing hydrogen peroxide - sodium thiosulphate method. The peracetic acid is determined iodometrically:
H2O2 + 2 NaI +H2SO4 |
→ |
I2 + Na2SO4 + 2 H2O |
I2 + Na2S2O3 |
→ |
2 NaI + Na2S2O3 |