R-200.20.030 [2016-03] Total Nitrogen in Malt – KJELDAHL

Application/Purpose

This method describes how to determine the total nitrogen in malt.

Scope of Application

Malt intended for use in beer brewing or elsewhere in the food industry.

Principle

from R-110.41.030 Nitrogen Content (Raw Protein) in Barley – KJELDAHL

The determination of nitrogen content according to Kjeldahl is divided into the following steps:

a. Digestion of the sample (oxidation of substances H2O, CO2, NH3)

b. Distillation (distillation of NH3 over into a boric acid solution)

c. Titration (determination of the amount of NH3 present in the receiver after distillation)

a. Digestion → 2 NH3 + H2SO4 → (NH4)2SO4

b. (NH4)2SO4 + 2 NaOH → Na2SO4 + 2 NH3 + 2 H2O
3 NH3 + H3BO3 → (NH4)3BO3

c. 2 (NH4)3BO3 + 3 H2SO4 → 3 (NH4)2SO4 + 2 H3BO3

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