B-420.22.157 [2020-10] 3-Hydroxy-2-butanone (Acetoin) – Headspace Method

Application/Purpose

Determination of 3-hydroxy-2-butanone (acetoin) in beer

Scope of Application

The method is suitable for beers of brewed to any original gravity or of any alcohol content.

Principle

The compound 3-hydroxy-2-butanone (acetoin) is derived from diacetyl and is created through the reductive activity of yeast. One further reaction mechanism for the formation of 3-hydroxy-2-butanone is condensation of both free and activated (bound to thiamine pyrophosphate [TPP]) acetaldehyde.

3-Hydroxybutanone is oxidized to 2,3-butanedione (diacetyl) by iron chloride in the presence of iron sulfate and determined using gas chromatography and the headspace analysis method.

 

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